在莫斯科一次图书书市上,苏联女子卡嘉(米歇尔·菲佛 饰)托推销员尼基把一份手稿交给伦敦出版商巴里·布莱尔(肖恩·康纳利 饰).尼基把手稿交给了英国情报部门"俄罗斯之家"."俄罗斯之家"发现这是一份关于苏联用以发动核战争的核能分析材料,于是派间谍内德(詹姆斯·福克斯 饰)和拉塞尔(罗伊·施奈德 饰)负责调查此事.他们照卡嘉的要求把手稿转给了巴里,巴里猜测这份手稿是一位名叫"丹特"的苏联科学家写的.内德说服巴里以作家代 理人的身份去苏联,设法核实手稿的内容.
巴里到达苏联后与卡嘉取得了联系,遇到了卡嘉之后一见钟情爱上了她,要在他的使命和这个既忠于国家又对他有情意的女人之间做出选择是多么的艰难.巴里通过卡嘉得知丹特是一个原子能专家,内德批示巴里向丹特提出一份"购物单",然后确定他对西方是否有价值.巴里了解到,有关方面都准备在达到目的之后牺牲卡嘉.巴里还发现丹特已经死了,他联系了苏联情报机关,答应把"购物单"交给他们,条件是苏联方面同意让卡嘉和她的家人获得自由.内德在最后才发现巴里的背叛,但他们已经来不及行动了,巴里向苏联交出的"购物单",然后回到里斯本与卡嘉汇合.
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