ABC电视台有望又一部根据漫威角色改编的电视剧——《特工卡特》Peggy Carter（Hayley Atwell）是美国队长的女友，也是特别短片《卡特探员》（Agent Carter）中的主角。1946年（电影《美国队长》的故事结束后），Peggy Carter的平静生活被彻底打破——当那些在海外作战的军人们返回家乡后，Carter发现自己被人彻底忽视了。如今她已经加盟秘密组织 SSR（Strategic Scientific Reserve，战略科学预备队），她必须在三件事之间找到平衡点：做好管理工作，为Howard Stark执行秘密任务，当一个美国单身女性。她以为自己一生中唯一爱过的男人Steve Rogers（美国队长）已经死了……她哪里知道他此刻正被困在冰中！与此同时，邪恶组织Zodiac依然在暗地里破坏着世界的和平与安定，Peggy Carter必须全力与其展开对抗。
卡特一行人前去影院调查死亡事件，在检查死者身上的伤势后，他们认同了观众死因为自相残杀的结果。苏萨在调查现场时偶然间发现了盛放生化武器的气罐，并不小心触动吸入了毒气，随即性情大变险些将汤普森特工掐死。 伊夫钦科医生拿走的生化武器数量足以毁灭半个城市，对此S.S.R召开会议讨论伊夫钦科医生偷走武器的目的，…
伊夫钦科医生回忆了1943年在俄国战场上利用催眠帮助一位截肢的病人消除痛苦。画面转回现在，另一方面，卡特的身份彻底被曝光，面临被战略科学军团的昔日工作伙伴审讯的局面。科学军团在给予她多重的拷问和胁迫后却未能从卡特口中得到想要的答案，并将库兹明斯基之死归咎于她身上，认为卡特是被斯塔克的谎言迷惑从而搅乱了…
1944年，利维坦组织胁迫大批各领域顶尖人才加入，包括被卡特特工解救的伊夫钦科医生(Dr.lvchenko)。 回国后，卡特希望伊夫钦科透露关于小女孩杀手的情报，但伊夫钦科却一无所知。
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