《超市特工》的男主角恰克-巴特维斯基(Chuck Bartowski)是“好又多”(Buy More)超市的电器修理员。十年前，他曾是斯坦福大学的一名高材生，大二的时候被同寝好友Bryce Larkin诬陷偷考卷，而被学校开除，拉金进而还抢走了恰克的女友，这一连串的打击让恰克从此以后一蹶不振，一直没有再交女朋友，曾经的梦想也基本放弃了。而拉金其实是一名特工，可是他背叛了组织，偷走了所有的国家机密，在逃跑过程中，他知道自己跑不掉了，就把资料全部发给了恰克，自己中弹身亡了。 恰克打开邮件后，奇妙的事情发生了，他的大脑竟然把所有的资料都存了起来，从此以后，恰克只要看到与资料中同样的图片，都会立刻像电脑搜索功能一样非常迅速地找到相应的资料。 这个特异功能使得恰克成为了国土安全局和中央情报局的头号保护对象，两个部门各派出一个特工来保护恰克。恰克更是深深的爱上了假扮他女友为掩护身份的中央情报局特工萨拉-沃克(Sarah Walker)。中情局和国家局开始建立新的Intersect交换机而希望脱离对CHUCK的依赖和保护，CHUCK更是希望能够早日脱离这种充满了谎言的生活并且和心爱的女孩Sarah开始真正的恋人生活。但现实与梦想总是有差距，CHUCK的梦想究竟能够实现吗，这时拉金重新出现，事情是否另有隐情呢......
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